Dynamic Nanostructures through Self-Assembly of Functional Polymers and Nanoparticles
발표자
박소정 (이화여자대학교)
연구책임자
박소정 (이화여자대학교)
초록
내용
The self-assembly of nanoscale building blocks into complex nanostructures with controlled structural anisotropy can open up new opportunities for realizing active nanomaterials exhibiting spatiotemporal structural transformations. Here, we adopt a combination of bottom-up DNA-directed self-assembly and top-down photothermal patterning to fabricate free-standing nanoparticle films with vertical and lateral heterogeneity. This approach involves the construction of multi-component plasmonic nanoparticle films by DNA-directed layer-by-layer (LbL) self-assembly, followed by on-demand lateral patterning by the direct photothermal writing method. The distinct plasmonic properties of metal nanoparticles constituting the multi-domain films enable photopatterning in a selective domain with precisely controlled vertical depths. The photopatterned films exhibit complex morphing actions instructed by the lateral and vertical patterns inscribed in the film as well as the information carried in DNA.