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발표분야
고분자구조 및 물성
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포스터발표
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Light-Responsive Shape-Changing BCP particles witht Dynamic Morphological Transformations
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초록

내용
We introduce a novel class of block copolymer particles that exhibit dynamic and reversible morphological transitions in response to light. The dynamic shape transition of those BCP particles is triggered by the spiropyran photoacid (SPPA) which induces the pH modulation upon photoisomerization. This pH modulation interacts with the P4VP, within the PS-b-P4VP particles, driving the morphological transitions. Under 420 nm light exposure, deprotonated SP formed SPPA affords the swelling of the P4VP domain, resulting in particle elongation. Importantly, the switching of shape and fluorescence properties of the BCP particles is rapid and reversible over multiple cycles of light exposure. Furthermore, shape-changeable BCP particles are integrated into hydrogel film to demonstrate reversible patterning and color changes upon activation by specific light wavelengths.

발표코드
3PS-187
발표일정
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