Corss-convergent synthesis of sequence-defined polymers
발표자
()
초록
내용
Sequence-defined polymers have attracted recent interest because of their promise as emerging materials for information storage, self-assembly, self-replication, and biomedical applications. We recently introduced a new synthetic pathway to sequence-defined polymers based on the deconvolution of the final sequence into an array of the dyads of two monomers. The dyads were sequentially converged to the target sequence-defined polymer in a minimum number of synthetic steps without using a large excess of reagents. The repetitive nature of the cross-convergent synthesis allows the process to be automated based on flow chemistry. We will discuss the synthesis and applications of these polymers with atomic precision.