Multifunctional Polymer Synthesis: Sequential Postpolymerization Modification of Aldehyde Polymers
발표자
()
초록
내용
PostPolymerization Modification(PPM) is important way to elaborating polymer performance, and PPM of polymer is one of the options for diversifying functional groups. However, finding conditions for polymerizing two or more reactive monomers, not touching other groups, and proceeding the selective modification bring on synthetic complications. In addition, the distribution of functional groups is uneven when structurally other monomers are polymerized. Synthesis and PPM of the multifunction homopolymers have emerged th detail the precision. However, the number of functional groups available is very limited. aldehydes, which easy to obtain and highly reactive to converted various functional groups, play important role in synthetic chemistry. Therefore, the Rhodium catalyzed C-H activation of the aldehyde pendent through the PPM forms ketone polymers, second functional group condensed between ketones and amines is synthesized and discussed as a new tool for synthetic complex polymers.