A Rational Entry to Cyclic Polymers <EM>via</EM> Spontaneous and Selective Cyclization Reactions
발표자
()
초록
내용
Although recent advances in chemistry have made it possible to synthesize polymers with various topologies, effective routes that selectively afford cyclic topology in high yield and quantity still remain limited. This is mostly due to difficulties associated with purification, and, in particular, the selectivity of macrocyclizations. In this work, effective synthetic methods for the cyclic polymers were developed by utilizing supramolecular chemistry1 and dynamic covalent chemistry.2 (1) D. Aoki et al., J. Am. Chem. Soc., 139, 6791 (2017). (2) D. Aoki et al., Angew. Chem. Int. Ed., 59, 4269 (2020).