Preperation of Core/shell Nanoparticles containing Diels-alder Copolymer with Inorganic oxide via In-situ Micellization
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초록
내용
In general, a block copolymer is used for uniform polymer particles. However, in this study, we were confirmed that the side chains of commercial polymer, Poly(4-vinylphenol) were modified through DCC coupling to synthesize random copolymers, and polymer particles were prepared in a simpler process only by cosolvent treatment. The synthesized polymer introduced a Diels-alder functional group to impart particle stability through thermal crosslinking properties. Also, a core-shell type particle composed of an inorganic oxide shell was successfully prepared using polymer nanoparticles as a template.