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「Macromolecular Research」 목차 고분자 과학과 기술 제 30 권 1 호 2019년 2월 121 Encapsulation of Peroxide Initiator in a Polyurea ShellIts Characteristics and Effect on MMA Polymerization Kinetics Hyeon Jin Kwon, Eun Ju Lee, Mi Rae Kim, Kang Ho Cheon, Hee Jung Park, and Kee Yoon Lee* Macromol. Res., 27, 198 2019 In this study, microcapsules with polyurea shells were prepared from oil-in-water O/W emulsion under various agitation speeds 230, 500, and 700 rpm to encapsulate cumene hydroperoxide CHP and tert-butyl peroxy-2-ethly hexanoate TBPEH Thus prepared microcapsule size and shell contents were observed to be decreased upon increasing the agitation speed. Differential scanning calorimetry DSC was used to measure and compare the effect on the reaction kinetics of the methyl methacrylate MMA radical polymerization in the presence of various initiators. When encapsulated initiator used instead of unencapsulated initiator the maximum conversion and maximum reaction rate...
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