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Program Scientific Program
INS2-0076

Superhydrophobic and Water-Repellent Coatings based on Waterborne MXene Nanocomposites for Antimicrobial Applications

Topic

S2. High-End Characterization/Polymer Physics/Properties

When and Where

Sep 29, 2026   16:40 - 17:05
Room 103

Session Chairs

Joe PATTERSON

Presenter(s)

Spiros Anastasiadis (Foundation for Research & Technology-Hellas and Univ. of Crete)

Co-Author(s)

Franceska Gojda (Foundation for Research & Technology-Hellas and Univ. of Crete), Maria Vlasiadi (Foundation for Research & Technology-Hellas and Univ. of Crete), Alexandros Thomos (Foundation for Research & Technology-Hellas and Univ. of Crete), Fanourios Krasanakis (Foundation for Research & Technology-Hellas), Minas M. Stylianakis (Foundation for Research & Technology-Hellas and Hellenic Mediterranean Univ.), Kiriaki Chrissopoulou (Foundation for Research & Technology-Hellas)

Abstract

The development of antifouling and antimicrobial surfaces that would prevent the transfer of bacteria has gained the scientific interest during the recent years. In this work, polymer nanocomposite coatings are developed to provide surfaces with antifouling and antimicrobial properties on frequently used surfaces in everyday life. This was achieved via deposition of waterborne nanocomposite coatings that contain the appropriate hydrophobic polymeric matrix and nano-additives, which provide the appropriate hierarchical roughness. While traditional methods typically employ 0D nanoparticles to achieve surface nano-structuring, the flake-like structure of Ti₃C₂Tₓ MXenes introduces roughness that extends into the micron-scale. Different smooth substrates were coated by a one-step spraying process and the surface properties were investigated as a function of the additive content. Moreover, ternary nanocomposite coatings were developed with MXenes and alumina nanoparticles by a single-step spraying of an aqueous suspension. This combination results in hierarchical surface structures (with micrometer- and nanometer-scale roughness), achieving excellent water repellence with significantly lower additive concentration than the one needed when single-type of nanoadditives were used. Due to the low Ti₃C₂Tₓ MXene content, the use of our approach extends beyond dark-colored applications, even in cases where the aesthetic result is critical. The nanohybrid coated surfaces exhibited mechanical and chemical durability, retaining their hydrophobicity after repeated abrasion cycles and under extreme pH conditions (pH 2 or 13). This study highlights the potential of MXenes as an innovative additive for next-generation water-repellent coatings. Acknowledgements: This research has been partially financed by the EU Horizon Europe Programme within project STOP (Grant Agreement 101057961) and project WISE (Grant Agreement 101138718).
Supported by
Korea Tourism Organization BUSAN TOURISM ORGANIZATION
Sponsored by
DONGWOO FINE-CHEM Co., Ltd. Korea Research Institute of Chemical Technology Advanced Materials Division Sejin CI DONGJIN SEMICHEM HAEDONG SCIENCE FOUNDATION COSMAX EcoProBM Young Eng. Sci. Doosan SAMSUNG SDI S-OIL 한국도레이과학진흥재단