Core Cross-Linked Block Polymer Micelles via Polymerization-Induced Self-Assembly
발표자
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초록
내용
Polymerization-induced self-assembly (PISA) is an appealing route to preparing block polymer micelle solution at high concentration by promoting in situ micellization of the emergent block polymer in solution. Generally, chain extension with an incompatible polymer to the solvent leads to spontaneous micellization. In this work, we propose controlled copolymerization of a monomer with a cross-linker for preparation of cross-linked block polymer micelles with diversified morphologies and increased structural stability in diluted environment.